Novel effects are increasingly being discovered when dissimilar materials are in contact ("hybrids"), often resulting in altogether new phenomena, materials with useful functionalities, or the ability to sense or control important material properties. The focus of this investigation is a hybrid material consisting of a thin nickel film on a vanadium oxide substrate; this hybrid material exhibits magnetic properties unlike any other magnetic material. In this case, the magnetic coercivity (defined as the resistance to a change in the direction of the magnetic fields for a ferromagnetic material) of the nickel reveals insights concerning the transition of the vanadium oxide from being an electrical conductor to becoming an insulator, called the metal-insulator transition (MIT). In turn, the MIT can be used to control the coercivity of the nickel. The vanadium oxide MIT is coincidental with a structural change at a well-defined "transition" temperature. At the thermal midpoint of the transition, crystallites of both phases coexist in equal portions, resulting in maximal structural entropy. The resulting inhomogeneity of the oxide structure causes stresses in the nickel (or other magnetic) film deposited on top. This provides a strong link between the nickel coercivity and the disorder in the oxide. The coercivity is low when the oxide is structurally uniform (above and below the MIT) and high when it is maximally disordered in the middle of the transition. The magnetic properties of nickel therefore provide a window into the MIT process. In turn, the MIT allows dramatic nonmagnetic control of the coercivity, which changes by several hundred percent within a narrow 10 K temperature range, unlike any other known magnetic material. Potential applications have been envisioned in two important, disparate energy related fields: energy driven magnetic recording and self-healing current fault limiters.
Schuller Group Research Findings "Giant Magnetic Effects Induced in Hybrid Materials" Published on DOE Website
Giant Magnetic Effects Induced in Hybrid Materials